Catalytic Kinetics: Chemistry and Engineering, Second Edition offers a unified view that homogeneous, heterogeneous, and enzymatic catalysis form the cornerstone of practical catalysis.
The book has an integrated, cross-disciplinary approach to kinetics and transport phenomena in catalysis, but still recognizes the fundamental differences between different types of catalysis. In addition, the book focuses on a quantitative chemical understanding and links the mathematical approach to kinetics with chemistry.
A diverse group of catalysts is covered, including catalysis by acids, organometallic complexes, solid inorganic materials, and enzymes, and this fully updated second edition contains a new chapter on the concepts of cascade catalysis. Finally, expanded content in this edition provides more in-depth discussion, including topics such as organocatalysis, enzymatic kinetics, nonlinear dynamics, solvent effects, nanokinetics, and kinetic isotope effects.
Key Features
- Fully revised and expanded, providing the latest developments in catalytic kinetics
- Bridges the gaps that exist between hetero-, homo- and enzymatic-catalysis
- Provides necessary tools and new concepts for researchers already working in the field of catalytic kinetics
- Written by internationally-renowned experts in the field
- Examples and exercises following each chapter make it suitable as an advanced course book
Chapter 1: Setting the Scene
- Abstract
- 1.1 History
- 1.2 Catalysis
- 1.3 Formal Kinetics
- 1.4 Acquisition of Kinetic Data
- 1.5 Kinetics and Thermodynamics
- 1.6 Examples and Exercises
Chapter 2: Catalysis
- Abstract
- 2.1 Homogeneous Catalysis
- 2.2 Heterogeneous Catalysis
- 2.3 Organocatalysis
- 2.4 Examples and Exercises
Chapter 3: Elementary Reactions
- Abstract
- 3.1 Reaction Rate Theory
- 3.2 Elementary Reactions in Solutions
- 3.3 Reaction Mechanism
- 3.4 Quasi-equilibrium Approximation
- 3.5 Relationship Between Thermodynamics and Kinetics
- 3.6 Transition State Theory of Surface Reactions
- 3.7 Rates of Reactions on Nonideal Surfaces
- 3.8 Deterministic and Stochastic Models
- 3.9 Microkinetic Modeling
- 3.10 Compensation Effect
- 3.11 Isotope Effects
- 3.12 Examples and Exercises
Chapter 4: Complex Reactions
- Abstract
- 4.1 Steady State Kinetics of Complex Reactions
- 4.2 Basic Routes of Complex Reactions
- 4.3 Single-Route Steady-State Reaction
- 4.4 Topological Analysis of Complex Reactions
- 4.5 Electrical Analogy of Reaction Networks
- 4.6 Thermodynamic Consistency of Rate Constants for Complex Networks
- 4.7 Kinetic Aspects of Selectivity
- 4.8 Parallel Reactions: Kinetic Coupling
- 4.9 Reduction of Complexity
- 4.10 Polynomial Kinetics
- 4.11 Examples and Exercises
Chapter 5: Homogeneous Catalytic Kinetics
- Abstract
- 5.1 Homogeneous Acid-Base Catalysis
- 5.2 Nucleophilic Catalysis
- 5.3 Catalysis by Metal Ions
- 5.4 Catalysis by Organometallic Complexes
- 5.5 Organocatalysis
- 5.6 Polymerization Catalysis
- 5.7 Examples and Exercises
Chapter 6: Enzymatic Kinetics
- Abstract
- 6.1 Enzymatic Catalysis
- 6.2 Cooperative Kinetics
- 6.3 Inhibition
- 6.4 Effects of pH
- 6.5 Single Molecule Enzymology
- 6.6 Enantioselectivity in Enzyme Catalyzed Reactions
- 6.7 Generalized Rate Laws for Enzymatic Reactions
- 6.8 Heterogeneous Systems/Immobilized Enzymes
- 6.9 Examples and Exercises
Chapter 7: Heterogeneous Catalytic Kinetics
- Abstract
- 7.1 Reactions on Ideal Surfaces
- 7.2 Reactions on Nonideal Surfaces
- 7.3 Selectivity
- 7.4 Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode
- 7.5 Solvent Effects
- 7.6 Ionic Species
- 7.7 Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions
- 7.8 Electrocatalytic Kinetics
- 7.9 Photocatalytic Kinetics
- 7.10 Nanokinetics
- 7.11 Examples and Exercises
Chapter 8: Kinetics of Catalytic Reactions With Multiple/Multifunctional Catalysts
- Abstract
- 8.1 General
- 8.2 Combined Catalytic and Noncatalytic Reactions
- 8.3 Multiple Catalysts of the Same Type
- 8.4 Multiple Catalysts of Different Types
- 8.5 Examples and Exercises
Chapter 9: Dynamic Catalysis
- Abstract
- 9.1 Transient Kinetics
- 9.2 Relaxation Methods
- 9.3 Temperature-Programmed Desorption
- 9.4 Oscillations
- 9.5 Dynamic Catalyst Changes
- 9.6 Examples and Exercises
Chapter 10: Mass Transfer and Catalytic Reactions
- Abstract
- 10.1 Catalytic Multi-Phase Systems
- 10.2 Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials
- 10.3 Liquid-Liquid Diffusion, Phase-Transfer Catalysis
- 10.4 Catalytic Two-Phase Systems
- 10.5 Mass Transfer and Enzymatic Kinetics
- 10.6 External Mass Transfer
- 10.7 Internal Diffusion and Selectivity
- 10.8 Internal Diffusion and Deactivation
- 10.9 Elucidation of the Impact of Mass Transfer
- 10.10 Three-Phase Systems
- 10.11 Examples and Exercises
Chapter 11: Kinetic Modeling
- Abstract
- 11.1 Basic Principles
- 11.2 Heuristic Design of Experiments
- 11.3 Parameter Estimation: Classical Methods
- 11.4 Parameter Estimation: Regression
- 11.5 Numerical Strategies
- 11.6 Analysis of Parameters
- 11.7 Model Discrimination
- 11.8 Software
- 11.9 Case Studies
- Catalysis: An Integrated Approach, B.A. Averill, J.A. Moulijn, R.A. van Santen, and P.W.N.M. van Leeuwen, Eds., Vol. 123 in Studies in Surface Science and Catalysis, 9780444829634, $ 235, 602 pp., 09/1999, Elsevier.
- Catalytic Kinetics, 1st ed., D. Murzin and T. Salmi, 9780444516053, $ 295, 492 pp., 09/2005, Elsevier.
- Heterogeneous Catalysis. Fundamentals and Applications, J. Ross, 9780444533630, $ 155, 232 pp., 09/2011, Elsevier.
- New and Future Developments in Catalysis, S. Suib, Ed., 07/2013, Elsevier.- Activation of Carbon Dioxide, 9780444538826, $ 210, 658 pp.- Batteries, Hydrogen Storage and Fuel Cells, 9780444538802, $ 210, 550 pp.- Catalysis by Nanoparticles, 9780444538741, $ 210, 512 pp.- Catalysis for Remediation and Environmental Concerns, 9780444538703, $ 210, 630 pp.- Catalytic Biomass Conversion, 9780444538789, $ 210, 412 pp.- Hybrid Materials, Composites, and Organocatalysts, 9780444538765, $ 210, 478 pp.- Solar Photocatalysis, 9780444538727, $ 210, 492 pp.
- Catalysis and Kinetics: Molecular Level Considerations, G.B. Marin, Ed., Vol. 44 in Advances in Chemical Engineering, 9780124199743, $ 245, 280 pp., 01/2014, Academic Press.
Post-graduate students and researchers in academia and industry working in catalysis, kinetics, and chemical engineering
